PAC Database - Detailed Chemical Data

Chemical Identity
Chemical CAS# UN# Health Code Numbers
Lithium chromate; (Lithium chromium oxide ) 14307-35-8 9134
14.01
4.01
11.01
14.02
4.08
4.05
7.01
7.00
4.09
4.10
Formula Synonyms
CrLi2O4 LITHIUM CHROMATE, CHROMATE DE LITHIUM (DOT FRENCH), CHROMIC ACID, DILITHIUM SALT, CHROMIUM LITHIUM OXIDE, CHROMIUM LITHIUM OXIDE (CRLI2O4), CROMATO DE LITIO (DOT SPANISH), DILITHIUM CHROMATE, DILITHIUM CHROMATE (LI2CRO4), LITHIUM CHROMATE (LI2CRO4), LITHIUM CHROMATE(VI), LITHIUM CHROMIUM OXIDE (LI2CRO4)
Physical Properties
Mol Wt State MP (°C) BP (°C) VP (Hg) VP (°C) SG LEL (ppm)
129.88 S 2.15
PAC Values
PAC Values (Original Units: mg/m3)
PAC-1 PAC-2 PAC-3
0.00065 6.5 39
Converted PAC Values (ppm)
PAC-1 PAC-2 PAC-3
0.00012 1.2 7.3
Technical Basis
A review of available sources did not identify exposure limits or acute toxicity data for lithium chromate. However, exposure limits for chromates were evaluated for TEEL development (CASRN: 1333-82-0), including TLV-TWA, TLV-STEL, PEL-STEL and IDLH (1990). Data sources were selected according to the hierarchy listed in Table 3.1. The IDLH was selected as the TEEL-3. The TLV-STEL was selected as the TEEL-1. A compound adjustment factor was applied to these exposure limits (Section 3.2.2). The TEEL-2 values were derived according to Table 3.5
• TEEL-1 = MW-adjusted TLV-STEL (chromic acid and chromates, as CrO3; CASRN:7440-47-3); 0.0005 mg/m³)
• TEEL-2 = TEEL-2/6
• TEEL-3 = MW-adjusted IDLH (1990, chromic acid and chromates, as CrO3; CASRN: 7440-47-3, 30 mg/m³)
This review generated TEEL-3 and TEEL-2 values consistent with Rev. 29A. The Rev. 29A TEEL-1 basis was a TLV-TWA for chromates, while the current basis is a higher priority source TLV-STEL for chromates (STEL > TWA).
References
Chemical information: https://pubchem.ncbi.nlm.nih.gov/compound/Lithium-chromate
Exposure limits, chromic acid and chromates (Cr(VI), as CrO3): https://www.osha.gov/chemicaldata/235
IDLH, chromic acid and chromates (Cr(VI), as CrO3): https://www.cdc.gov/niosh/idlh/1333820.html
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