PAC Database - Detailed Chemical Data

Chemical Identity
Chemical CAS# UN# Health Code Numbers
Nickel 7440-02-0 2881
15.01
4.01
11.01
15.02
4.08
8.00
11.00
4.09
4.06
4.10
Formula Synonyms
Ni METAL CATALYST, DRY, ALCAN 123, ALCAN 756, C.I. 77775, C.I. 77775, CATALIZADOR DE METAL, SECO (DOT SPANISH), CATALIZADOR DE NÍQUEL, SECO (DOT SPANISH), CATALYSEUR AU NICKEL, SEC (DOT FRENCH), CATALYSEUR MÉTALLIQUE, SEC (DOT FRENCH), CELMET, DNI 20, E 12, E 12 (METAL), FIBREX, FIBREX (METAL FIBER), FIBREX P, FUKUDA 287, HCA 1, N 1, N 154, NDHT 90, NDT 90, NI 0901-S, NI 123, NI 255AC, NI 270, NI 287, NI 4303-S, NI 4303T, NICKEL, NICKEL 270, NICKEL CATALYST, NICKEL CATALYST, DRY, NICKEL ELEMENT, NICKEL METAL: ELEMENTAL NICKEL, NICKEL PARTICLES, NICKEL SPONGE, NICKLE CATALYST, WET, NIKKO 255, NOVAMET 4SP, NOVAMET NI 255, NP 2, PULVERIZED NICKEL, R 239, R 239 (CATALYST), RANEY ALLOY, RANEY NICKEL, RCH 55/5, SF 300, T 123, T 123 (METAL), TRIMAG, TRIMAG (METAL)
Physical Properties
Mol Wt State MP (°C) BP (°C) VP (Hg) VP (°C) SG LEL (ppm)
58.69 S 1455 2913 1510 8.9
PAC Values
PAC Values (Original Units: mg/m3)
PAC-1 PAC-2 PAC-3
0.24 50 99
Converted PAC Values (ppm)
PAC-1 PAC-2 PAC-3
0.100 21 41
Technical Basis
A review of available sources identified exposure limits (IDLH, LOC, TWAs, OEL-STEL) and acute toxicity data (TDLo, LD50) for several species and routes. Data sources were selected according to the hierarchy listed in Table 3.1. Toxicity data were selected according to type of exposure, species, and route according to the hierarchies stated in Sections 3.3.1, 3.3.2, and evaluated using factors in Tables 3.2, 3.3, and 3.4. The 1990 and 1994 IDLHs were evaluated. The 1990 IDLH was an approximate value, derived from an exposure limit. The 1994 IDLH was less than the Level of Concern and the same order of magnitude of the TLV-TWA; as such, it was determined overly conservative. Considering the availability of acute toxicity data, neither IDLH was selected. Instead, the most preferred species and route toxicity data, a rat intraperitoneal LD50 was selected as the TEEL-3 basis. The LOC was selected as the TEEL-2. The OEL-STEL (15-minute, Germany AGS) was selected as the TEEL-1.
• PAC-1 = TEEL-1 = OEL-STEL (15-minute, Germany, 0.24 mg/m3)
• PAC-2 = TEEL-2 = LOC (0.05 g/m3)
• PAC-3 = TEEL-3 = Rat intraperitoneal LD50 (250 mg/kg)
This review generated PAC-3 and PAC-2 values consistent with Rev. 29A and a PAC-1 inconsistent with Rev. 29A. The Rev. 29A TEEL-1 basis was a TLV-TWA, while the current TEEL-1 is an OEL-STEL, a more preferred source (see note, Table 3.5).
References
Chemical information: https://pubchem.ncbi.nlm.nih.gov/compound/Nickel
IDLH: https://www.cdc.gov/niosh/idlh/7440020.html
Exposure limits (TLV-TWA): https://www.osha.gov/chemicaldata/509
OELs (STEL, TWA): https://ilv.ifa.dguv.de/limitvalues/43321
Rat intraperitoneal LD50. Industrial Medicine., 15(482), 1946. Retrieved from: https://pubchem.ncbi.nlm.nih.gov/compound/Nickel
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