PAC Database - Detailed Chemical Data

Chemical Identity
Chemical CAS# UN# Health Code Numbers
Potassium dichromate 7778-50-9 1479
13.00
14.01
4.01
11.01
14.02
4.08
4.05
7.01
8.00
11.00
Formula Synonyms
Cr2K2O7 POTASSIUM BICHROMATE, BICHROMATE OF POTASH, BICHROME, CHROMIC ACID, DIPOTASSIUM SALT, CHROMIUM POTASSIUM OXIDE (K2CR2O7), DICHROMIC ACID (H2CR2O7), DIPOTASSIUM SALT, DICHROMIC ACID DIPOTASSIUM SALT, DICHROMIC ACID, DIPOTASSIUM SALT, DIPOTASSIUM BICHROMATE, DIPOTASSIUM BICHROMATE (K2CR2O7), DIPOTASSIUM DICHROMATE, DIPOTASSIUM DICHROMATE (K2CR2O7), DIPOTASSIUM DICHROMIUM HEPTAOXIDE, IOPEZITE, NA1479, POTASSIUM DICHROMATE, POTASSIUM DICHROMATE (K2(CR2O7)), POTASSIUM DICHROMATE (K2CR2O7), POTASSIUM DICHROMATE (VI), POTASSIUM DICHROMATE VI, POTASSIUM DICHROMATE(VI), SRM 935A
Physical Properties
Mol Wt State MP (°C) BP (°C) VP (Hg) VP (°C) SG LEL (ppm)
294.19 S 398 2.68
PAC Values
PAC Values (Original Units: ppm)
PAC-1 PAC-2 PAC-3
0.026 0.28 1.8
Converted PAC Values (mg/m3)
PAC-1 PAC-2 PAC-3
0.31 3.4 22
Technical Basis
A review of available sources found toxicity data for this chemical. Although the rat LD50 was the more preferred species, its source, a corporate summary report vs. peer-reviewed journal, was less reliable. Therefore, mouse oral LD50 data was selected as the TEEL-3 basis. TEEL-2 and TEEL-1 values were calculated from this TEEL-3, in accordance with guidelines in the handbook (Table 3.5.)

TEEL-1 = TEEL-2/11
TEEL-2 = TEEL-3/6
TEEL-3 = Mouse oral LD50 (190 mg/kg)

This review generated slightly more conservative values than those reported in Rev. 29A. In Rev. 29A, the TEEL-3 was estimated from molecular weight adjusted Cr(VI) TLV and IDLH values, while the current recommendation is based on Hazardous Substance Database toxicity data. It was deemed preferable to use data associated with the chemical of interest, if credible, versus a component that requires a weight-adjustment.
References
https://pubchem.ncbi.nlm.nih.gov/source/hsdb/1238
https://pubchem.ncbi.nlm.nih.gov/compound/24502
https://nj.gov/health/eoh/rtkweb/documents/fs/1564.pdf
https://pubchem.ncbi.nlm.nih.gov/compound/Potassium-dichromate
https://www.epa.gov/sites/default/files/2016-09/documents/chromium-compounds.pdf
https://www.osha.gov/chemicaldata/537
https://www.cdc.gov/niosh/docs/2013-128/pdfs/2013_128.pdf
https://www.atsdr.cdc.gov/ToxProfiles/tp7.pdf
https://www.cdc.gov/niosh/idlh/1333820.html
National Technical Information Service. Vol. OTS0545929
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