PAC Database - Detailed Chemical Data

Chemical Identity
Chemical CAS# UN# Health Code Numbers
Silicofluoric acid; (Fluorosilicic acid) 16961-83-4 1778
14.01
4.01
11.01
14.02
4.05
7.01
8.00
11.00
4.07
3.03
Formula Synonyms
H2F6Si FLUOROSILICIC ACID, ACIDE FLUOROSILICIQUE (DOT FRENCH), ACIDE FLUOSILICIQUE (DOT FRENCH), ACIDE HYDROFLUOROSILICIQUE (DOT FRENCH), ACIDE HYDROFLUOSILICIQUE (DOT FRENCH), ACIDO FLUOROSILÍCICO (DOT SPANISH), ACIDO FLUOSILÍCICO (DOT SPANISH), ACIDO HIDROFLUOROSILÍCICO (DOT SPANISH), ACIDO HIDROFLUOSILÍCICO (DOT SPANISH), DIHYDROGEN HEXAFLUOROSILICATE, DIHYDROGEN HEXAFLUOROSILICATE(2-), FLUOROSILIC ACID, FLUOROSILICIC ACID (H2SIF6), FLUOSILICIC ACID, HEXAFLUOROSILICIC ACID, HEXAFLUOSILICIC ACID, HYDROFLUOROSILICIC ACID, HYDROFLUOSILIC ACID, HYDROFLUOSILICIC ACID, HYDROGEN HEXAFLUOROSILICATE, HYDROGEN HEXAFLUOROSILICATE (H2SIF6), SAND ACID, SILICOFLUORIC ACID, SILICON HEXAFLUORIDE DIHYDRIDE, HFSA
Physical Properties
Mol Wt State MP (°C) BP (°C) VP (Hg) VP (°C) SG LEL (ppm)
144.09 L 1.0407 @ 17.5°C
PAC Values
PAC Values (Original Units: mg/m3)
PAC-1 PAC-2 PAC-3
1.3 14 85
Converted PAC Values (ppm)
PAC-1 PAC-2 PAC-3
0.22 2.4 14
Technical Basis
A review of limited available data sources identified the following: LD50 toxicity data for oral exposure. This source was evaluated using factors in Tables 3.2, 3.3, and 3.4 and was the basis for the TEEL-3 calculation. TEEL-2 and TEEL-1 values were derived according to Table 3.5.
• TEEL-1 = TEEL-2/11
• TEEL-2 = TEEL-3/6
• TEEL-3 = Rat oral LD50 (430 mg/kg)
This review generated TEEL values that are more conservative than those found in Rev. 29A. In Rev. 29A the TEEL-3 basis was an IDLH (1990) for fluorides and that was MW-adjusted, however this review’s proposed data is derived directly from the compound's acute toxicity data.
References
Rat oral LD50: CDC/NIOSH; The Registry for Toxic Effects of Chemical Substances- Silicate (2-), hexafluoro-, dihydrogen (16961-83-4). Retrieved from https://pubchem.ncbi.nlm.nih.gov/compound/Hexafluorosilicic-acid
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