PAC Database - Detailed Chemical Data

Chemical Identity
Chemical CAS# UN# Health Code Numbers
Benzenamine, sulfate (2:1) 542-16-5
14.01
14.02
11.01
4.07
11.00
7.01
7.11
4.06
3.02
13.00
Formula Synonyms
C12.H16.N2.O4.S
Physical Properties
Mol Wt State MP (°C) BP (°C) VP (Hg) VP (°C) SG LEL (ppm)
284.3294 S 1.38 13000
PAC Values
PAC Values (Original Units: mg/m3)
PAC-1 PAC-2 PAC-3
1.2 13 79
Converted PAC Values (ppm)
PAC-1 PAC-2 PAC-3
0.10 1.1 6.8
Technical Basis
A review of available sources did not identify exposure limits or acute toxicity data for sulfate benzenamine (2:1). Reported GHS health hazards (H302, H311, H331, Category 3) indicate mid-level health hazards, approximately equivalent to an HHR=2. In addition, analysts evaluated available AEGLs for the components of this compound, sulfuric acid (CASRN: 7664-93-9, AEGL-3 = 160 mg/m3) and aniline (CASRN: 62-53-3, 76 mg/m3), both which align more closely with an HHR=3. Considering this, analysts assumed an HHR=3 as the TEEL-3 basis (Section 3.4.5). TEEL-2 and TEEL-1 values were derived according to Table 3.5.
• PAC-1 = TEEL-1 = TEEL-2/11
• PAC-2 = TEEL-2 = TEEL-3/6
• PAC-3 = TEEL-3 = HHR=3
This review generated PAC values inconsistent with Rev. 29A. The Rev. 29A TEEL-1 basis was a TLV-TWA for particles not otherwise specified (Section 3.5.2), from which the TEEL-2 and TEEL-3 were derived (Table 3.5). The current TEEL-3 basis is an assumed HHR=2, from analysis of GHS health hazard statements and consideration of the compound components, from which TEEL-2 and TEEL-1 were derived (Table 3.5).
References
Chemical information and GHS ratings: https://pubchem.ncbi.nlm.nih.gov/compound/10951.
AEGLs for sulfuric acid (CASRN: 7664-93-9): https://www.epa.gov/aegl/sulfuric-acid-results-aegl-program
AEGLs for aniline (CASRN: 62-53-3): https://www.epa.gov/aegl/aniline-results-aegl-program
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